MATERIAL SAFETY DATA SHEET EQUILON MSDS: 01947ET 01/04/99 HAVOLINE WHEEL BEARING & CHASSIS GREASE TELEPHONE NUMBER: 24 HOUR EMERGENCY ASSISTANCE GENERAL MSDS ASSISTANCE EQUIVA SERVICES: 877-276-7283 877-276-7285 CHEMTREC: 800-424-9300 NAME AND ADDRESS: EQUILON ENTERPRISES LLC PRODUCT STEWARDSHIP P.O. BOX 674414 HOUSTON, TX 77267-4414 LEGEND: N.D. - NOT DETERMINED N.A. - NOT APPLICABLE N.T- NOT TESTED < - LESS THAN > - GREATER THAN Name: HAVOLINE WHEEL BEARING & CHASSIS GREASE Product Code: 01947 Date Issued: 1999-01-04 Supersedes: 1997-11-12 Company: EQUILON ENTERPRISES LLC ________________________________________________________________________________ 1.NAME ________________________________________________________________________________ MATERIAL IDENTITY Product Code and Name: 01947 HAVOLINE WHEEL BEARING & CHASSIS GREASE Chemical Name and/or Family or Description: Greases _______________________________________________________________________________ 2. COMPOSITION/INFORMATION ON INGREDIENTS _______________________________________________________________________________ THE CRITERIA FOR LISTING COMPONENTS IN THE COMPOSITION SECTION IS AS FOLLOWS: CARCINOGENS ARE LISTED WHEN PRESENT AT 0.1 % OR GREATER; COMPONENTS WHICH ARE OTHERWISE HAZARDOUS ACCORDING TO OSHA ARE LISTED WHEN PRESENT AT 1.0 % OR GREATER; NON-HAZARDOUS COMPONENTS ARE LISTED AT 3.0 % OR GREATER. THIS IS NOT INTENDED TO BE A COMPLETE COMPOSITIONAL DISCLOSURE. REFER TO SECTION 14 FOR APPLICABLE STATES' RIGHT TO KNOW AND OTHER REGULATORY INFORMATION. Product and/or Component(s) Carcinogenic According to: OSHA IARC NTP OTHER NONE X _ _ _ _ _ Composition: (Sequence Number and Chemical Name) Seq. Chemical Name CAS Number Range in % ____ ____________________________________________ ______________ ____________ 01 # Hydrotreated heavy naphthenic petroleum 64742-52-5 50.00-64.99 distillates 02 Lithium complex thickener and proprietary 20.00-34.99 additives 03 # Solvent-dewaxed petroleum residual oil 64742-62-7 10.00-19.99 PRODUCT IS NON-HAZARDOUS ACCORDING TO OSHA (1910.1200). # COMPONENT, BY DEFINITION, IS CONSIDERED HAZARDOUS ACCORDING TO OSHA BECAUSE IT CARRIES THE PERMISSIBLE EXPOSURE LIMIT (PEL) FOR MINERAL OIL MIST. Exposure Limits referenced by Sequence Number in the Composition Section Seq. Limit ____ _________________________________________________________________________ 01 5 mg/m3 TWA-OSHA (MINERAL OIL MIST) 01 5 mg/m3 TWA-ACGIH (MINERAL OIL MIST) 01 10 mg/m3 STEL ACGIH (MINERAL OIL MIST) 03 5 mg/m3 TWA-OSHA (MINERAL OIL MIST) 03 5 mg/m3 TWA-ACGIH (MINERAL OIL MIST) 03 10 mg/m3 STEL ACGIH (MINERAL OIL MIST) _______________________________________________________________________________ 3. HAZARD IDENTIFICATION _______________________________________________________________________________ EMERGENCY OVERVIEW Appearance: Red grease Odor: Not determined WARNING STATEMENT _________________ NONE CONSIDERED NECESSARY HMIS NFPA Health: 0 Reactivity: 0 Health: 0 Reactivity: 0 Flammability: 1 Special : - Flammability: 1 Special : - POTENTIAL HEALTH EFFECTS EYE SKIN INHALATION INGESTION Primary Route of Exposure: X X X _ _ _ _ EFFECTS OF OVEREXPOSURE Acute: Eyes: May cause minimal irritation, experienced as temporary discomfort. Skin: Brief contact is not irritating. Prolonged contact, as with clothing wetted with material, may cause defatting of skin or irritation, seen as local redness with possible mild discomfort. Other than the potential skin irritation effects noted above, acute (short term) adverse effects are not expected from brief skin contact; see other effects, below, and Section 11 for information regarding potential long term effects. Inhalation: Product not volatile at ambient temperatures. Vapors or mist in high concentrations, as generated from spraying or heating in an enclosed space, may cause minimal irritation. Ingestion: If more than several mouthfuls are swallowed, abdominal discomfort, nausea, and diarrhea may occur. Sensitization Properties: Unknown. Chronic: No adverse effects have been documented in humans as a result of chronic exposure. Section 11 may contain applicable animal data. Medical Conditions Aggravated by Exposure: Because of its defatting properties, prolonged and repeated skin contact may aggravate an existing dermatitis (skin condition). Other Remarks: Material from high pressure equipment, pinhole leaks, or high pressure line failure can penetrate the skin and, if not properly treated, can cause severe injury, including disfigurement, loss of function, or even require amputation of the affected area. To prevent such serious injury, immediate medical attention should be sought even if the injection injury appears to be minor. _______________________________________________________________________________ 4. FIRST AID MEASURES _______________________________________________________________________________ Eyes: Flush eyes with plenty of water for several minutes. Get medical attention if eye irritation persists. Skin: Wash skin with plenty of soap and water for several minutes. Get medical attention if skin irritation develops or persists. Ingestion: If more than several mouthfuls of this material are swallowed, give two glasses of water (16 oz.). Get medical attention. Inhalation: If irritation, headache, or drowsiness occurs, remove to fresh air. Other Instructions: High pressure injection of material can cause severe injury. Failure to debride the wound of all residual material can result in disfigurement, loss of function, or may require amputation of the affected area. Remove and dry-clean or launder clothing soaked or soiled with this material before reuse. Dry cleaning of contaminated clothing may be more effective than normal laundering. Inform individuals responsible for cleaning of potential hazards associated with handling contaminated clothing. _______________________________________________________________________________ 5. FIRE-FIGHTING MEASURES _______________________________________________________________________________ Ignition Temperature - AIT (degrees F): Not determined. Flash Point (degrees F): Not determined. Flammable Limits (%): Lower: Not determined. Upper: Not determined. Recommended Fire Extinguishing Agents And Special Procedures: Use water spray, dry chemical, foam, or carbon dioxide to extinguish flames. Use water spray to cool fire-exposed containers. Water or foam may cause frothing. Unusual or Explosive Hazards: None Extinguishing Media Which Must Not Be Used: Not determined. Special Protective Equipment for Firefighters: Other than normal protective fire-fighting equipment, no special equipment or procedures required. _______________________________________________________________________________ 6. ACCIDENTAL RELEASE MEASURES (Transportation Spills: CHEMTREC (800)424-9300) _______________________________________________________________________________ Procedures in Case of Accidental Release, Breakage or Leakage: Contain spill if possible, contain with absorbent materials such as clay or soil, and shovel up. Avoid skin and eye contact. _______________________________________________________________________________ 7. HANDLING AND STORAGE _______________________________________________________________________________ Precautions to be Taken in Handling: Minimum feasible handling temperatures should be maintained. Storage: Periods of exposure to high temperatures should be minimized. Water contamination should be avoided. _______________________________________________________________________________ 8. EXPOSURE CONTROLS/PERSONAL PROTECTION _______________________________________________________________________________ Protective Equipment (Type) Eye/Face Protection: Safety glasses, chemical type goggles, or face shield recommended to prevent eye contact. Skin Protection: Workers should wash exposed skin several times daily with soap and water. Soiled work clothing should be laundered or dry-cleaned. Respiratory Protection: Airborne concentrations should be kept to lowest levels possible. If vapor, mist or dust is generated and the occupational exposure limit of the product, or any component of the product, is exceeded, use appropriate NIOSH or MSHA approved air purifying or air supplied respirator after determining the airborne concentration of the contaminant. Air supplied respirators should always be worn when airborne concentration of the contaminant or oxygen content is unknown. Ventilation: Adequate to meet component occupational exposure limits (see Section 2). Exposure Limit for Total Product: None established for product; refer to Section 2 for component exposure limits. _______________________________________________________________________________ 9. PHYSICAL AND CHEMICAL PROPERTIES _______________________________________________________________________________ Appearance: Red grease Odor: Not determined Boiling Point (degrees F): Not determined. Melting/Freezing point (degrees F): Not applicable. Specific Gravity (water=1): .93 pH of undiluted product: Not applicable. Vapor Pressure: Not determined. Viscosity: Not determined. VOC Content: Not determined. Vapor Density (air=1): Not applicable. Solubility in Water (%): Not determined. Other: None _______________________________________________________________________________ 10. STABILITY AND REACTIVITY _______________________________________________________________________________ This Material Reacts Violently With: (If Others is checked below, see comments for details) Air Water Heat Strong Oxidizers Others None of These X _ _ _ _ _ _ Comments: None Products Evolved When Subjected to Heat or Combustion: Toxic levels of carbon monoxide, carbon dioxide, irritating aldehydes and ketones, and combustion products or compounds of lithium. Hazardous Polymerizations: DO NOT OCCUR _______________________________________________________________________________ 11. TOXICOLOGICAL INFORMATION _______________________________________________________________________________ TOXICOLOGICAL INFORMATION(ANIMAL TOXICITY DATA) Median Lethal Dose Oral: LD50 Believed to be > 5.00 g/kg (rat) practically non-toxic Inhalation: Not determined. Dermal: LD50 Believed to be > 2.00 g/kg (rabbit) practically non-toxic Irritation Index, Estimation of Irritation (Species) Skin: (Draize) Believed to be < .50 /8.0 (rabbit) no appreciable effect Eyes: (Draize) Believed to be < 15.00 /110 (rabbit) no appreciable effect Sensitization: Not determined. Other: None _______________________________________________________________________________ 12. DISPOSAL CONSIDERATIONS _______________________________________________________________________________ Waste Disposal Methods This product has been evaluated for RCRA characteristics and does not meet the criteria of a hazardous waste if discarded in its purchased form. Under RCRA, it is the responsibility of the user of the product to deter- mine at the time of disposal, whether the product meets RCRA criteria for hazardous waste. This is because product uses, transformations, mixtures, processes, etc. may render the resulting materials hazardous. Remarks None _______________________________________________________________________________ 13. TRANSPORT INFORMATION _______________________________________________________________________________ Transportation DOT: Proper Shipping Name: Not regulated IMDG: Proper Shipping Name: Not regulated ICAO: Proper Shipping Name: Not regulated TDG: Proper Shipping Name: Not regulated _______________________________________________________________________________ 14. REGULATORY INFORMATION _______________________________________________________________________________ Federal Regulations: SARA Title III: Section 302/304 Extremely Hazardous Substances Seq. Chemical Name CAS Number Range in % ____ ____________________________________________ ______________ ___________ None Section 302/304 Extremely Hazardous Substances (CONT) Seq. TPQ RQ ____ __________ __________ None Section 311 Hazardous Categorization: Acute Chronic Fire Pressure Reactive N/A X _ _ _ _ _ _ Section 313 Toxic Chemical Chemical Name CAS Number Concentration ____________________________________________ ______________ _____________ None CERCLA 102(a)/DOT Hazardous Substances: (+ indicates DOT Hazardous Substance) Seq. Chemical Name CAS Number Range in % ____ ____________________________________________ ______________ ___________ None CERCLA/DOT Hazardous Substances (Sequence Numbers and RQ's): Seq. RQ ____ __________ None TSCA Inventory Status: This product, or its components, are listed on or are exempt from the Toxic Substance Control Act (TSCA) Chemical Substance Inventory. Other: None. State Regulations: California Proposition 65: The following detectable components of this product are substances, or belong to classes of substances, known to the State of California to cause cancer and/or reproductive toxicity. Chemical Name CAS Number ____________________________________________ ______________ None International Regulations: WHMIS Classification: Not controlled Canada Inventory Status: This product, or its components, are listed on or are exempt from the Canadian Domestic Substance List (DSL). EINECS Inventory Status: Not determined. Australia Inventory Status: Not determined. Japan Inventory Status: Not determined. _______________________________________________________________________________ 15. ENVIRONMENTAL INFORMATION _______________________________________________________________________________ Aquatic Toxicity: Not determined. Mobility: Not determined. Persistence and Biodegradability: Not determined. Potential to Bioaccumulate: Not determined. Remarks: None _______________________________________________________________________________ 16. OTHER INFORMATION _______________________________________________________________________________ None THE INFORMATION CONTAINED IN THIS DATA SHEET IS BASED ON THE DATA AVAILABLE TO US AT THIS TIME, AND IS BELIEVED TO BE ACCURATE BASED UPON THAT DATA. IT IS PROVIDED INDEPENDENTLY OF ANY SALE OF THE PRODUCT, FOR PURPOSE OF HAZARD COMMUNICATION. IT IS NOT INTENDED TO CONSTITUTE PRODUCT PERFORMANCE INFORMATION, AND NO EXPRESS OR IMPLIED WARRANTY OF ANY KIND IS MADE WITH RESPECT TO THE PRODUCT, UNDERLYING DATA OR THE INFORMATION CONTAINED HEREIN. YOU ARE URGED TO OBTAIN DATA SHEETS FOR ALL PRODUCTS YOU BUY, PROCESS, USE OR DISTRIBUTE, AND ARE ENCOURAGED TO ADVISE THOSE WHO MAY COME IN CONTACT WITH SUCH PRODUCTS OF THE INFORMATION CONTAINED HEREIN. TO DETERMINE THE APPLICABILITY OR EFFECT OF ANY LAW OR REGULATION WITH RESPECT TO THE PRODUCT, YOU SHOULD CONSULT WITH YOUR LEGAL ADVISOR OR THE APPROPRIATE GOVERNMENT AGENCY. WE WILL NOT PROVIDE ADVICE ON SUCH MATTERS, OR BE RESPONSIBLE FOR ANY INJURY FROM THE USE OF THE PRODUCT DESCRIBED HEREIN. THE UNDERLYING DATA, AND THE INFORMATION PROVIDED HEREIN AS A RESULT OF THAT DATA, IS THE PROPERTY OF EQUIVA SERVICES, LLC AND IS NOT TO BE THE SUBJECT OF SALE OR EXCHANGE WITHOUT THE EXPRESS WRITTEN CONSENT OF EQUIVA SERVICES, LLC. Date: 1999-01-04 New X Revised, Supersedes: 1997-11-12 __________ _ _ __________ Inquiries regarding MSDS should be directed to: Equiva Services LLC Manager Product Stewardship P.O. Box 674414 Houston, TX 77267-4414 _______________________________________________________________________________ 17. PRODUCT LABEL Label Date: 1999-01-04 _______________________________________________________________________________ READ AND UNDERSTAND MATERIAL SAFETY DATA SHEET BEFORE HANDLING OR DISPOSING OF PRODUCT. THIS LABEL COMPLIES WITH THE REQUIREMENTS OF THE OSHA HAZARD COMMUNICATION STANDARD (29 CFR 1910.1200) FOR USE IN THE WORKPLACE. THIS LABEL IS NOT INTENDED TO BE USED WITH PACKAGING INTENDED FOR SALE TO CONSUMERS AND MAY NOT CONFORM WITH THE REQUIREMENTS OF THE CONSUMER PRODUCT SAFETY ACT OR OTHER RELATED REGULATORY REQUIREMENTS. 01947 HAVOLINE WHEEL BEARING & CHASSIS GREASE WARNING STATEMENT _________________ NONE CONSIDERED NECESSARY PRECAUTIONARY MEASURES ______________________ -Avoid prolonged breathing of vapor, mist, or gas. -Workers should wash exposed skin several times daily with soap and water. FIRST AID _________ Eye Contact: Flush eyes with plenty of water for several minutes. Get medical attention if eye irritation persists. Skin Contact: Wash skin with plenty of soap and water for several minutes. Get medical attention if skin irritation develops or persists. Ingestion: If more than several mouthfuls of this material are swallowed, give two glasses of water (16 oz.). Get medical attention. Inhalation: If irritation, headache, or drowsiness occurs, remove to fresh air. Note to Physician: High pressure injection of material can cause severe injury. Failure to debride the wound of all residual material can result in disfigurement, loss of function, or may require amputation of the affected area. FIRE ____ In case of fire, use water spray, dry chemical, foam or carbon dioxide. Water may cause frothing. Use water spray to cool fire-exposed containers. Chemical Name CAS Number Range in % ____________________________________________ _____________ ____________ # Hydrotreated heavy naphthenic petroleum 64742-52-5 50.00-64.99 distillates Lithium complex thickener and proprietary 20.00-34.99 additives # Solvent-dewaxed petroleum residual oil 64742-62-7 10.00-19.99 PRODUCT IS NON-HAZARDOUS ACCORDING TO OSHA (1910.1200). # COMPONENT, BY DEFINITION, IS CONSIDERED HAZARDOUS ACCORDING TO OSHA BECAUSE IT CARRIES THE PERMISSIBLE EXPOSURE LIMIT (PEL) FOR MINERAL OIL MIST. Pennsylvania Special Hazardous Substance(s) CAS Number Range in % ____________________________________________ _____________ ____________ None HMIS NFPA Health: 0 Reactivity: 0 Health: 0 Reactivity: 0 Flammability: 1 Special : - Flammability: 1 Special : - Transportation DOT: Proper Shipping Name: Not regulated CAUTION: Misuse of empty containers can be hazardous. Empty containers can be hazardous if used to store toxic, flammable, or reactive materials. Cutting or welding of empty containers might cause fire, explosion or toxic fumes from residues. Do not pressurize or expose to open flame or heat. Keep container closed and drum bungs in place. Name and Address: Equilon Enterprises LLC P.O. Box 674414 Houston ,TX 77267-4414 TRANSPORTATION EMERGENCY: (877)276-7283 CHEMTREC: (800)424-9300 HEALTH EMERGENCY: (877)276-7283 }